TETRABROMOBISPHENOL A ALLYL ETHER

PRODUCT IDENTIFICATION

CAS NO

25327-89-3

 

EINECS NO. 246-850-8
FORMULA (CH3)2C[C6H2(Br)2OCH2CH=CH2]2
MOL WT. 624.03

H.S. CODE

2908.10

TOXICITY

 

SYNONYMS 2,2-bis(4-(allyloxy)-3,5-dibromophenyl)-Propane;
1,1'-(1-methylethylidene)bis(3,5-dibromo-4-(2-propenyloxy)-Benzene; 1,1'-(1-Methylethylidene)bis(3,5-dibromo-4-(2-propenyloxy)benzene); Tetrabromo Bisphenol A (allyl ether); 四溴醚; 1,1'-Isopropylidenbis[4-(allyloxy)-3,5-dibrombenzol] (German); 1,1'-isopropilidenbis[4-(aliloxi)-3,5-dibromobenceno] (Spanish); 1,1'-isopropylidènebis[4-(allyloxy)-3,5-dibromobenzène] (French);
SMILES  

CLASSIFICATION

 

GENERAL DESCRIPTION

Tetrabromobisphenol A (TBBPA) has the largest market among brominated flame retardants. It is a white to off-white powder melting point of 180-184°C; soluble in methanol and ether. TBBPA is produced by the bromination of BPA (bisphenol A) with various solvents such as halocarbon alone, hydrobromic acid, aqueous alkyl monoethers, acetic acid ( with sodium acetate to improve colouror) or methanol (methyl bromide is expected as a co-product). Tetrabromobisphenol A (TBBPA) is used as a reactive flame retardant in epoxy, vinyl esters and polycarbonate resins. The main application of TBBPA in epoxy resins is in PCB (printed circuit boards) where the bromine content may be 20% by weight. It is used also as a flame retardant in polymers such as ABS, polystyrenes, phenolic resins, adhesives, paper, and textiles and others. TBBPA can be combined with a synergist such as antimony trioxide for maximum flame retardant performance. TBBPA may also be used as a parent compound for the production of other commercial flame retardants, such as tetrabromobisphenol A bis(2-hydroxyethyl ether), tetrabromobisphenol A dibromopropylether, tetrabromobisphenol A bis(allylether), tetrabromobisphenol A carbonate oligomers, and tetrabromobisphenol A brominated epoxy oligomer.

PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL STATE white to off-white crystalline powder

MELTING POINT

118 - 120 C
BOILING POINT  
SPECIFIC GRAVITY  

SOLUBILITY IN WATER

Insoluble
pH  
VAPOR DENSITY  

AUTOIGNITION

 

NFPA RATINGS

 

REFRACTIVE INDEX

 

FLASH POINT

 

STABILITY Stable under ordinary conditions

APPLICATIONS

Flame retardant in plastics, polyurethane, paper and textiles. Fire extinguishing media.
SALES SPECIFICATION

APPEARANCE

white to off-white crystalline powder

BROMINE CONTENT

50% min

MELTING POINT

115 C min

TRANSPORTATION
PACKING 25kgs in bag
HAZARD CLASS

 

UN NO.  
GENERAL DESCRIPTION OF FLAME RETARDANT AGENT

Flame Retardant are substances that can be chemically inserted into the polymer molecule or be physically blended in polymers after polymerization to suppress, reduce, delay or modify the propagation of a flame through a plastic materials. There are several classes of flame retardants; Halogenated Hydrocarbons (Chlorine and Bromine containing compounds and reactive flame retardants), Inorganic flame retardants ( Boron compounds, Antimony oxides, Aluminium Hydroxide, molybdenum compounds, zinc and magnesium oxides ), Phosphorous containing compounds (Organic phosphate esters, phosphates, halogenated phosphorus compounds and inorganic phosphorus containing salts).

Class of Flame Retardants

  • Inorganic
    • Metal hydroxides
      • Aluminium hydroxide
      • Magnesium hydroxide
      • Orthers
    • Antimony compounds
      • Antimony trioxide
      • antimony pentoxide
      • Sodium antimonate
      • Others
    • Boron compounds
      • Boric acid
      • Borax
      • Zinc borate
      • Others
    • Other metal compounds
      • Molybdenum compounds
      • Titanium compounds
      • Zirconium compounds
      • Zinc compounds
        • Zinc stannate
        • Zinc hydroxy-stannate
        • Others
      • Others
    • Phosphorus compounds
      • Red phosphorus
      • Ammonium polyphosphate
      • Others
    • Other inorganic flame retardants
      • ammonium sulfamate
      • ammonium bromide
      • Others
  • Halogenated organic
    • Brominated
      • Tetrabromobisphenol A
      • Decabromodiphenyl ether
      • Octabromobiphenyl ether
      • Tetrabromobiphenyl ether
      • Hexabromocyclododecane
      • Tribromophenol
      • Bis(tribromophenoxy) ethane
      • Tetrabromobisphenol A polycarbonate oligomers
      • Tetrabromobisphenol A epoxy oligomers
      • Others
    • Chlorinated
      • Chlorinated paraffins
      • Bis(hexachlorocyclopentadieno)cyclo-octane
      • Others
  • Organophosphoros
    • Non-halogenated compounds
      • phosphate esters
        • Ttrialkyl phosphates
        • Triaryl phosphates
        • Aryl-alkyl phosphates
        • Others
      • polyols
      • phosphonium derivatives
      • phosphonates
      • Others
    • Halogenated phosphates
      • Tris(1-chloro- 2-propyl) phosphate
      • Tris(2-chloroethyl) phosphate
      • Tris(2,3-dibromopropyl)phosphate
      • Others
  • Nitrogen-based
    • Polyurethanes
    • Polyamides
    • Melamine and its salts
    • Guanidine compounds
    • Others